Hey Angelo,
Thanks again for the speedy reply. I've done as you suggested and modified the Feed Settings to not use the Feeburner feed, which is fine. Yet validating still givs me the exact same issue, regardless. I did try wiping plugin cache as well, to see if that was causing an issue.
The thing the error seems to indicate is
Sorry
This feed does not validate.
Server returned HTTP Error 404: Not Found
Now, the error does seem to indicate that there's a problem with an itunes Image, stating it has a 404. I'm sorta at my wits end for what to do.